A metabolomic approach to quality determination and authentication of raw plant material in the fragrance field. Iris rhizomes: a case study.
Identifieur interne : 000255 ( Main/Exploration ); précédent : 000254; suivant : 000256A metabolomic approach to quality determination and authentication of raw plant material in the fragrance field. Iris rhizomes: a case study.
Auteurs : Jerome Masson [Italie] ; Erica Liberto [Italie] ; Hugues Brevard [France] ; Carlo Bicchi [Italie] ; Patrizia Rubiolo [Italie]Source :
- Journal of chromatography. A [ 1873-3778 ] ; 2014.
Descripteurs français
- KwdFr :
- Chromatographie en phase liquide à haute performance (méthodes), Iris (composition chimique), Iris (métabolisme), Métabolomique (méthodes), Méthode des moindres carrés (MeSH), Parfum (analyse), Reproductibilité des résultats (MeSH), Rhizome (composition chimique), Rhizome (métabolisme), Spectrométrie de masse (méthodes).
- MESH :
- analyse : Parfum.
- composition chimique : Iris, Rhizome.
- métabolisme : Iris, Rhizome.
- méthodes : Chromatographie en phase liquide à haute performance, Métabolomique, Spectrométrie de masse.
- Méthode des moindres carrés, Reproductibilité des résultats.
English descriptors
- KwdEn :
- MESH :
- chemical , analysis : Perfume.
- chemistry : Iris, Rhizome.
- metabolism : Iris, Rhizome.
- methods : Chromatography, High Pressure Liquid, Mass Spectrometry, Metabolomics.
- Least-Squares Analysis, Reproducibility of Results.
Abstract
This study aimed to discriminate 22 samples of commercial Iris rhizomes (orris root) by species and origin (Iris germanica (Morocco), I. albicans (Morocco), I. pallida (Morocco), I. pallida (China), I. pallida (Italy)) by applying a strategy derived from those adopted in metabolomics. The specimens' fingerprints from conventional analysis methods (LC-UV and/or LC-MS) were unable to provide clear discrimination. A strategy combining UHPLC/TOF-HRMS, in positive and negative modes, with multivariate statistical methods was therefore applied. Exact mass/retention time (EMRT) pairs obtained by UHPLC-TOF/HRMS were successfully submitted to statistical processing by principal component analysis (PCA), partial least square discriminant analysis (PLS-DA), and then orthogonal partial least square-discriminant analysis (OPLS-DA), to extract the discriminating EMRT pairs through their trend views. 146 EMRT pairs were selected on the basis of their trend views, because they significantly varied, and 104 of them were included to discriminate between species and origins. 32 of them were tentatively identified as discriminating markers (flavonoids, isoflavonoids, triterpenoids, benzophenone derivatives and related glycosides …) from the reference database created on the basis of Iris genus components reported in the literature: eight of them specific for I. albicans, four for I. germanica, five for I. pallida (Italy), five for I. pallida (China), and ten for I. pallida (Morocco). The reliability of this strategy was confirmed by identifying species and origin of two unknown samples submitted to the same analytical procedure.
DOI: 10.1016/j.chroma.2014.09.076
PubMed: 25441349
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream PubMed, to step Corpus: 000559
- to stream PubMed, to step Curation: 000557
- to stream PubMed, to step Checkpoint: 000599
- to stream Main, to step Merge: 000255
- to stream Main, to step Curation: 000255
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">A metabolomic approach to quality determination and authentication of raw plant material in the fragrance field. Iris rhizomes: a case study.</title><author><name sortKey="Masson, Jerome" sort="Masson, Jerome" uniqKey="Masson J" first="Jerome" last="Masson">Jerome Masson</name><affiliation wicri:level="1"><nlm:affiliation>Robertet SA, Research Division, 37 Avenue Sidi Brahim, F-06130 Grasse, France; Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino, Italy.</nlm:affiliation><country xml:lang="fr">Italie</country><wicri:regionArea>Robertet SA, Research Division, 37 Avenue Sidi Brahim, F-06130 Grasse, France; Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino</wicri:regionArea><wicri:noRegion>I-10125 Torino</wicri:noRegion></affiliation></author><author><name sortKey="Liberto, Erica" sort="Liberto, Erica" uniqKey="Liberto E" first="Erica" last="Liberto">Erica Liberto</name><affiliation wicri:level="1"><nlm:affiliation>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino, Italy.</nlm:affiliation><country xml:lang="fr">Italie</country><wicri:regionArea>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino</wicri:regionArea><wicri:noRegion>I-10125 Torino</wicri:noRegion></affiliation></author><author><name sortKey="Brevard, Hugues" sort="Brevard, Hugues" uniqKey="Brevard H" first="Hugues" last="Brevard">Hugues Brevard</name><affiliation wicri:level="3"><nlm:affiliation>Robertet SA, Research Division, 37 Avenue Sidi Brahim, F-06130 Grasse, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Robertet SA, Research Division, 37 Avenue Sidi Brahim, F-06130 Grasse</wicri:regionArea><placeName><region type="region" nuts="2">Provence-Alpes-Côte d'Azur</region><settlement type="city">Grasse</settlement></placeName></affiliation></author><author><name sortKey="Bicchi, Carlo" sort="Bicchi, Carlo" uniqKey="Bicchi C" first="Carlo" last="Bicchi">Carlo Bicchi</name><affiliation wicri:level="1"><nlm:affiliation>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino, Italy.</nlm:affiliation><country xml:lang="fr">Italie</country><wicri:regionArea>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino</wicri:regionArea><wicri:noRegion>I-10125 Torino</wicri:noRegion></affiliation></author><author><name sortKey="Rubiolo, Patrizia" sort="Rubiolo, Patrizia" uniqKey="Rubiolo P" first="Patrizia" last="Rubiolo">Patrizia Rubiolo</name><affiliation wicri:level="1"><nlm:affiliation>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino, Italy. Electronic address: patrizia.rubiolo@unito.it.</nlm:affiliation><country xml:lang="fr">Italie</country><wicri:regionArea>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino</wicri:regionArea><wicri:noRegion>I-10125 Torino</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2014">2014</date><idno type="RBID">pubmed:25441349</idno><idno type="pmid">25441349</idno><idno type="doi">10.1016/j.chroma.2014.09.076</idno><idno type="wicri:Area/PubMed/Corpus">000559</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000559</idno><idno type="wicri:Area/PubMed/Curation">000557</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000557</idno><idno type="wicri:Area/PubMed/Checkpoint">000599</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000599</idno><idno type="wicri:Area/Main/Merge">000255</idno><idno type="wicri:Area/Main/Curation">000255</idno><idno type="wicri:Area/Main/Exploration">000255</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">A metabolomic approach to quality determination and authentication of raw plant material in the fragrance field. Iris rhizomes: a case study.</title><author><name sortKey="Masson, Jerome" sort="Masson, Jerome" uniqKey="Masson J" first="Jerome" last="Masson">Jerome Masson</name><affiliation wicri:level="1"><nlm:affiliation>Robertet SA, Research Division, 37 Avenue Sidi Brahim, F-06130 Grasse, France; Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino, Italy.</nlm:affiliation><country xml:lang="fr">Italie</country><wicri:regionArea>Robertet SA, Research Division, 37 Avenue Sidi Brahim, F-06130 Grasse, France; Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino</wicri:regionArea><wicri:noRegion>I-10125 Torino</wicri:noRegion></affiliation></author><author><name sortKey="Liberto, Erica" sort="Liberto, Erica" uniqKey="Liberto E" first="Erica" last="Liberto">Erica Liberto</name><affiliation wicri:level="1"><nlm:affiliation>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino, Italy.</nlm:affiliation><country xml:lang="fr">Italie</country><wicri:regionArea>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino</wicri:regionArea><wicri:noRegion>I-10125 Torino</wicri:noRegion></affiliation></author><author><name sortKey="Brevard, Hugues" sort="Brevard, Hugues" uniqKey="Brevard H" first="Hugues" last="Brevard">Hugues Brevard</name><affiliation wicri:level="3"><nlm:affiliation>Robertet SA, Research Division, 37 Avenue Sidi Brahim, F-06130 Grasse, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Robertet SA, Research Division, 37 Avenue Sidi Brahim, F-06130 Grasse</wicri:regionArea><placeName><region type="region" nuts="2">Provence-Alpes-Côte d'Azur</region><settlement type="city">Grasse</settlement></placeName></affiliation></author><author><name sortKey="Bicchi, Carlo" sort="Bicchi, Carlo" uniqKey="Bicchi C" first="Carlo" last="Bicchi">Carlo Bicchi</name><affiliation wicri:level="1"><nlm:affiliation>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino, Italy.</nlm:affiliation><country xml:lang="fr">Italie</country><wicri:regionArea>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino</wicri:regionArea><wicri:noRegion>I-10125 Torino</wicri:noRegion></affiliation></author><author><name sortKey="Rubiolo, Patrizia" sort="Rubiolo, Patrizia" uniqKey="Rubiolo P" first="Patrizia" last="Rubiolo">Patrizia Rubiolo</name><affiliation wicri:level="1"><nlm:affiliation>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino, Italy. Electronic address: patrizia.rubiolo@unito.it.</nlm:affiliation><country xml:lang="fr">Italie</country><wicri:regionArea>Dipartimento di Scienza e Tecnologia del Farmaco, Università di Torino, Via P. Giuria 9, I-10125 Torino</wicri:regionArea><wicri:noRegion>I-10125 Torino</wicri:noRegion></affiliation></author></analytic><series><title level="j">Journal of chromatography. A</title><idno type="eISSN">1873-3778</idno><imprint><date when="2014" type="published">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chromatography, High Pressure Liquid (methods)</term><term>Iris (chemistry)</term><term>Iris (metabolism)</term><term>Least-Squares Analysis (MeSH)</term><term>Mass Spectrometry (methods)</term><term>Metabolomics (methods)</term><term>Perfume (analysis)</term><term>Reproducibility of Results (MeSH)</term><term>Rhizome (chemistry)</term><term>Rhizome (metabolism)</term></keywords><keywords scheme="KwdFr" xml:lang="fr"><term>Chromatographie en phase liquide à haute performance (méthodes)</term><term>Iris (composition chimique)</term><term>Iris (métabolisme)</term><term>Métabolomique (méthodes)</term><term>Méthode des moindres carrés (MeSH)</term><term>Parfum (analyse)</term><term>Reproductibilité des résultats (MeSH)</term><term>Rhizome (composition chimique)</term><term>Rhizome (métabolisme)</term><term>Spectrométrie de masse (méthodes)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Perfume</term></keywords><keywords scheme="MESH" qualifier="analyse" xml:lang="fr"><term>Parfum</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Iris</term><term>Rhizome</term></keywords><keywords scheme="MESH" qualifier="composition chimique" xml:lang="fr"><term>Iris</term><term>Rhizome</term></keywords><keywords scheme="MESH" qualifier="metabolism" xml:lang="en"><term>Iris</term><term>Rhizome</term></keywords><keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Chromatography, High Pressure Liquid</term><term>Mass Spectrometry</term><term>Metabolomics</term></keywords><keywords scheme="MESH" qualifier="métabolisme" xml:lang="fr"><term>Iris</term><term>Rhizome</term></keywords><keywords scheme="MESH" qualifier="méthodes" xml:lang="fr"><term>Chromatographie en phase liquide à haute performance</term><term>Métabolomique</term><term>Spectrométrie de masse</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Least-Squares Analysis</term><term>Reproducibility of Results</term></keywords><keywords scheme="MESH" xml:lang="fr"><term>Méthode des moindres carrés</term><term>Reproductibilité des résultats</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">This study aimed to discriminate 22 samples of commercial Iris rhizomes (orris root) by species and origin (Iris germanica (Morocco), I. albicans (Morocco), I. pallida (Morocco), I. pallida (China), I. pallida (Italy)) by applying a strategy derived from those adopted in metabolomics. The specimens' fingerprints from conventional analysis methods (LC-UV and/or LC-MS) were unable to provide clear discrimination. A strategy combining UHPLC/TOF-HRMS, in positive and negative modes, with multivariate statistical methods was therefore applied. Exact mass/retention time (EMRT) pairs obtained by UHPLC-TOF/HRMS were successfully submitted to statistical processing by principal component analysis (PCA), partial least square discriminant analysis (PLS-DA), and then orthogonal partial least square-discriminant analysis (OPLS-DA), to extract the discriminating EMRT pairs through their trend views. 146 EMRT pairs were selected on the basis of their trend views, because they significantly varied, and 104 of them were included to discriminate between species and origins. 32 of them were tentatively identified as discriminating markers (flavonoids, isoflavonoids, triterpenoids, benzophenone derivatives and related glycosides …) from the reference database created on the basis of Iris genus components reported in the literature: eight of them specific for I. albicans, four for I. germanica, five for I. pallida (Italy), five for I. pallida (China), and ten for I. pallida (Morocco). The reliability of this strategy was confirmed by identifying species and origin of two unknown samples submitted to the same analytical procedure. </div></front></TEI><affiliations><list><country><li>France</li><li>Italie</li></country><region><li>Provence-Alpes-Côte d'Azur</li></region><settlement><li>Grasse</li></settlement></list><tree><country name="Italie"><noRegion><name sortKey="Masson, Jerome" sort="Masson, Jerome" uniqKey="Masson J" first="Jerome" last="Masson">Jerome Masson</name></noRegion><name sortKey="Bicchi, Carlo" sort="Bicchi, Carlo" uniqKey="Bicchi C" first="Carlo" last="Bicchi">Carlo Bicchi</name><name sortKey="Liberto, Erica" sort="Liberto, Erica" uniqKey="Liberto E" first="Erica" last="Liberto">Erica Liberto</name><name sortKey="Rubiolo, Patrizia" sort="Rubiolo, Patrizia" uniqKey="Rubiolo P" first="Patrizia" last="Rubiolo">Patrizia Rubiolo</name></country><country name="France"><region name="Provence-Alpes-Côte d'Azur"><name sortKey="Brevard, Hugues" sort="Brevard, Hugues" uniqKey="Brevard H" first="Hugues" last="Brevard">Hugues Brevard</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Sante/explor/MaghrebDataLibMedV2/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000255 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000255 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Sante
|area= MaghrebDataLibMedV2
|flux= Main
|étape= Exploration
|type= RBID
|clé= pubmed:25441349
|texte= A metabolomic approach to quality determination and authentication of raw plant material in the fragrance field. Iris rhizomes: a case study.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:25441349" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \
| NlmPubMed2Wicri -a MaghrebDataLibMedV2
| This area was generated with Dilib version V0.6.38. |  |